Product ID:SULFURIC ACID 60 DEGREE
MSDS Date:09/01/1991
FSC:6810
NIIN:00-848-7312
MSDS Number: BMSXP

SANCHEZ AND ASSOCIATES

605 S MILLIKEN AVE SUITE E
ONTARIO, CA 91761
US

Emergency Phone: 714-370-3921

Info Phone: 714-370-3921

Cage: LO689

SANCHEZ AND ASSOCIATES

1649 COLTON, CA 92324 US

Telephone: 714-370-3921

Cage: LO689

SULFURIC ACID (SARA III)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 77.7%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50 (ORAL RAT) = 2140 MG/KG BODY WEIGHT
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE - CORROSIVE. INGESTION: CAUSES
MOUTH, THROAT, ESOPHAGUS, STOMACH BURNS, GASTRIC PERFORATION AND
EVEN DEATH. INHALATION: FUMES CAN CAUSE DAMAGE TO NASAL AND
RESPIRATORY PASSAGES. SKIN: BURNING, C HARRING AND DEEP ULCERATION.
EYES: CAUSES SEVERE DAMAGE AND EVEN BLINDNESS VERY RAPIDLY. CHRONIC
- NONE KNOWN.
Effects of Overexposure:INGESTION: CAUSES MOUTH, THROAT, ESOPHAGUS,
STOMACH BURNS, GASTRIC PERFORATION, AND EVEN DEATH. FUMES CAN CAUSE
DAMAGE TO NASAL AND RESPIRATORY PASSAGES. CAN CAUSE BURNING,
CHARRING, AND DEEP ULCERATI ON OF SKIN. CAUSES SEVERE EYE DAMAGE
AND EVEN BLINDNESS VERY RAPIDLY.
Medical Cond Aggravated by Exposure:SKIN IRRITATION MAY BE AGGRAVATED
IN PERSONS WITH EXISTING SKIN LESIONS. BREATHING OF SPRAYS
(SULFURIC ACID MISTS) MAY AGGRAVATE ACUTE OR CHRONIC ASTHMA AND
OTHER CHRONIC PULMONARY DISEASE.

First Aid:SPEED IS ESSENTIAL. START FIRST AID AND GET MEDICAL CARE AT
ONCE. EYES AND SKIN: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. HOLD
EYELIDS OPEN. INHALATON: REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF
NEED ED. INGESTION: DO NOT INDUCE VOMITING. IF CONSCIOUS, DRINK 2-3
GLASSES OF WATER. TAKE MILK OF MAGNESIA. KEEP WARM AND QUIET.

Flash Point:NONE
Extinguishing Media:USE DRY CHEMICAL. WATER MAY BE USED TO KEEP
FIRE-EXPOSED CONTAINERS COOL UNTIL FIRE IS OUT.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:SULFURIC ACID REACTS WITH MOST METALS TO
RELEASE HYDROGEN GAS WHICH CAN BE EXPLOSIVE WITH AIR. WATER/FOAM
MAY CAUSE FROTHING AND IF SPRAYED INTO HOT ACID.

Spill Release Procedures:COVER SMALL SPILLS WITH NA BICARBONATE,SODA
ASH,OR LIME.PICK UP WITH ABSORBING MATERIAL & TRANSFER TO A
SUITABLE CONTAINER.DIKE TO CONTAIN LARGE SPILL.PUMP LIQUID TO
SALVAGE TANK.REMAINING LIQUID MAY BE TAKEN UP ON SAND,CLAY &
SHOVELED INTO CONTAINER
Neutralizing Agent:LIME OR SODA ASH

Handling and Storage Precautions:STORE IN A COOL, DRY PLACE, IN TIGHTLY
CLOSED CONTAINERS.
Other Precautions:KEEP IN AN AREA WITH AN ACID RESISTANT CEMENT FLOOR.
DO NOT BREATHE SPRAYS OR MISTS. DO NOT INGEST. DO NOT GET IN EYES,
ON SKIN, OR ON CLOTHING. DILUTE ACID BY ADDING IT SLOWLY TO WATER
AND MIXING AND COOLING IT. NEVER ADD WATER TO ACID.

Respiratory Protection:USE NIOSH/MSHA APPROVED MIST FILTER, ACID GAS
CARTRIDGE RESPIRATOR. USE POSITIVE PRESSURE SELF-CONTAINED
BREATHING APPARATUS OR AIR-SUPPLIED RESPIRATOR FOR EMERGENCY
CONDITIONS WHERE EXPOSURE LIMITS A RE EXCEEDED.
Ventilation:MECHANICAL
Protective Gloves:PVC
Eye Protection:SPLASH-PROOF SAFETY GOGGLES/FACE SHIELD
Other Protective Equipment:SINK, SAFETY SHOWER, EYEWASH FOUNTAIN,
OXYGEN, FULL-BODY PROTECTIVE CLOTHING
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING.
Supplemental Safety and Health
DANGER! CAUSES SEVERE BURNS. REACTS VIOLENTLY WITH WATER. CONTENTS MAY
BE UNDER PRESSURE OF EXPLOSIVE HYDROGEN GAS. HIGHLY REACTIVE AND
CAPABLE OF IGNITING COMBUSTIBLE MATERIAL ON CONTACT. EMPTY CONTA
INER MAY BE HAZARDOUS SINCE IT MAY RETAIN PRODUCT RESIDUES. ALL
HAZARD PRECAUTIONS MUST BE OBSERVED.

HCC:C1
Boiling Pt:B.P. Text:535F,279C
Vapor Pres:0.01
Spec Gravity:1.71
pH:< 1
Evaporation Rate & Reference:< 1 (ETHER = 1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, VISCOUS LIQUID WITH NO ODOR.
Percent Volatiles by Volume:5-10

Stability Indicator/Materials to Avoid:YES
STRONG BASES, COMBUSTIBLE MATERIALS, POWDERED METALS, ORGANIC
MATERIALS, WATER
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES, MOISTURE
Hazardous Decomposition Products:OXIDES OF SULFUR, HYDROGEN SULFIDE,
HYDROGEN GAS

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE AND FEDERAL REGULATIONS.THIS MATERIAL IS RCRA
HAZARDOUS WASTE D002,CORROSIVE & D003,REACTIVE.SPILLS ARE SUBJECT
TO CERLCA REPORTING REQUIREMEN TS:RQ=1000 LBS. ELIMINATE ALL
SOURCES OF IGNITION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.